Live Chat - Meet new people is an app that lets you video chat with random people. Basically it's like a modern Chatroulette where, if you get on well with someone, you can become friends.
You can skip from one video chat to another, viewing them over your Android device and starting a conversation with anyone who seems interesting. If the person seems to be a good conversationalist you can carry on talking with them, or if they're annoying or just not that compelling, you can quickly move on to the next video chat.
An interesting security measure in Live Chat - Meet new people is that by default the camera does not focus on your interlocutor – the image shows up blurry. Thanks to this feature you normally won't end up seeing anything you really don't want to see.
Live Chat - Meet new people is an interesting alternative to your standard hookup apps like Badoo or Meetic that makes use of video chats instead of photos and profile descriptions.